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1.8 Specific Leakage Current (Cross-Over Current)

The specific leakage current, $I_{\rm leak}$ (A/ $m^3$), models the effect of species cross-over from one electrode to another across the electrolyte. In addition to the source terms expressed by Equations  1.3-1 through 1.3-9:

For PEMFC and SOFC:


$\displaystyle S_{{\rm H}_2}$ $\textstyle =$ $\displaystyle -\frac{M_{w,{\rm H}_2}}{2F} I_{\rm leak}$ (1.8-1)
       
$\displaystyle S_{{\rm O}_2}$ $\textstyle =$ $\displaystyle -\frac{M_{w,{\rm O}_2}}{4F} I_{\rm leak}$ (1.8-2)
       
$\displaystyle S_{{\rm H}_2{\rm0}}$ $\textstyle =$ $\displaystyle \frac{M_{w,{\rm H}_2{\rm0}}}{2F} I_{\rm leak} > 0$ (1.8-3)

For Electrolysis:


$\displaystyle S_{{\rm H}_2}$ $\textstyle =$ $\displaystyle \frac{M_{w,{\rm H}_2}}{2F} I_{\rm leak}$ (1.8-4)
       
$\displaystyle S_{{\rm O}_2}$ $\textstyle =$ $\displaystyle \frac{M_{w,{\rm O}_2}}{4F} I_{\rm leak}$ (1.8-5)
       
$\displaystyle S_{{\rm H}_2{\rm0}}$ $\textstyle =$ $\displaystyle -\frac{M_{w,{\rm H}_2{\rm0}}}{2F} I_{\rm leak}$ (1.8-6)


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