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You can specify the anode settings for the SOFC With Unresolved Electrolyte Model by enabling the Anode Interface option in the Electrolyte and Tortuosity tab in the SOFC Model dialog.
Once you enable the Anode Interface option, you select the surface that represents the anode electrode interface with the electrolyte from the corresponding Zone(s) list and click Apply. You can do this for as many zones as you need. When you are finished setting up the anode interface, click the OK button.